Synthesis and Characterization of Two Novel Naphthalenediimide/ Zinc Phosphonate Crystalline Materials Precipitated from Different Solvents

Página final1756por
Página inicial1748por
Volume9por
AutorPoly-Anna Vera Melo, Barbra
AutorFernando Gregório Junior, Denis
AutorTroilo de Oliveira, Matheus
Autorde Jesus Trindade, Fabiane
Autorvan de Streek, Jacco
AutorFurlan Ferreira, Fabio
AutorBrochsztain, Sergio
Data de Acesso2024-11-11T19:20:57Z
Ano de publicação2024por
AbstractHybrid naphthalenediimide/zinc phosphonate materials (NDI/Zn) were prepared by mixing solutions of N,N′-bis(2- phosphonoethyl)-1,4,5,8-naphthalenediimide (PNDI) and zinc nitrate, resulting in the precipitation of the desired compounds. Samples precipitated from water and N,N-dimethylformamide (DMF) were produced. The obtained samples had the expected elemental composition, and the presence of naphthalenediimides (NDI) was ascertained by infrared and UV−visible spectroscopy. All the samples were crystalline, according to powder X-ray diffraction. Nitrogen adsorption isotherms showed the presence of porosity in the NDI/Zn samples. Mesopores with a diameter = 4.1mm were present in the sample from DMF, with total pore volume reaching 0.13 cm3/g.eng
ProveniênciaSubmitted by Sergio Brochsztain (sergio.brochsztain@ufabc.edu.br) on 2024-10-29T23:53:00Z No. of bitstreams: 1 (49) ACS Omega 2024.pdf: 7180988 bytes, checksum: cbb9e6aef7ca1e4ff153c3034d800f06 (MD5)eng
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ProveniênciaMade available in DSpace on 2024-11-11T19:20:57Z (GMT). No. of bitstreams: 1 (49) ACS Omega 2024.pdf: 7180988 bytes, checksum: cbb9e6aef7ca1e4ff153c3034d800f06 (MD5) Previous issue date: 2024eng
RegiãoSudestepor
ResumoHybrid naphthalenediimide/zinc phosphonate materials (NDI/Zn) were prepared by mixing solutions of N,N′-bis(2- phosphonoethyl)-1,4,5,8-naphthalenediimide (PNDI) and zinc nitrate, resulting in the precipitation of the desired compounds. Samples precipitated from water and N,N-dimethylformamide (DMF) were produced. The obtained samples had the expected elemental composition, and the presence of naphthalenediimides (NDI) was ascertained by infrared and UV−visible spectroscopy. All the samples were crystalline, according to powder X-ray diffraction. Nitrogen adsorption isotherms showed the presence of porosity in the NDI/Zn samples. Mesopores with a diameter = 4.1 nm were present in the sample from DMF, with total pore volume reaching 0.13 cm3/g.por
Agência de financiamentoFundação de Amparo à Pesquisa do Estado de São Paulopor
Formatoapplication/pdf*
URIhttps://deposita.ibict.br/handle/deposita/690
Idiomaengpor
InstituiçãoUniversidade Federal do ABCpor
PaísEstados unidospor
Título do periódicoACS Omegapor
Tipo de acessoopenAccesspor
Palavra ChaveMetal Phosphonateseng
Palavra ChaveZinc Phosphonateeng
Palavra ChaveNaphthalenediimideseng
Palavra ChaveMesoporous Materialseng
Área de conhecimento CNPqQuímicapor
TítuloSynthesis and Characterization of Two Novel Naphthalenediimide/ Zinc Phosphonate Crystalline Materials Precipitated from Different Solventspor
TipoArtigopor

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